Adams Flea & Tick Home Spray
Safety Data Sheet
Date of issue: 11/03/2015 Revision date: 05/18/2018 Version: 1.0
05/18/2018
EN (English US)
Page 1
SECTION 1: Identification
1.1. Identification
Product form
:
Mixture
Trade name
:
Adams Flea & Tick Home Spray
Synonyms
:
EPA Reg. No.: 2724-822-89459, 100525088, RF2177 WB Carpet RTU
1.2. Recommended use and restrictions on use
Recommended use
:
Insecticide. Insect growth regulator.
Restrictions on use
:
Keep out of reach of children. Avoid breathing dust. Avoid contact with eyes, skin and clothing.
1.3. Supplier
1.4. Emergency telephone number
1-800-234-2269
Emergency number
:
1-800-424-9300 - CHEMTREC
1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Not classified
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
No labeling applicable
2.3. Other hazards which do not result in classification
Other hazards not contributing to the
classification
:
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this
product is not considered hazardous.
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name
Product identifier
%
Etofenprox
(CAS-No.) 80844-07-1
0.5
Piperonyl butoxide
(CAS-No.) 51-03-6
2
(s)-Methoprene Technical
(CAS-No.) 65733-16-6
0.01
Other ingredients
(CAS-No.) N/A
Balance
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures after inhalation
:
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact
:
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical
advice/attention.
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First-aid measures after eye contact
:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention.
First-aid measures after ingestion
:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
Do NOT induce vomiting unless directed to do so by medical personnel.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after skin contact
:
May cause skin irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media
:
Use extinguishing agent suitable for surrounding fire.
Unsuitable extinguishing media
:
Avoid heavy hose streams.
5.2. Specific hazards arising from the chemical
Reactivity
:
The product is non-reactive under normal conditions of use, storage and transport.
5.3. Special protective equipment and precautions for fire-fighters
Protection during firefighting
:
Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures
:
Ventilate spillage area.
6.1.2. For emergency responders
Protective equipment
:
Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: Exposure controls/personal protection.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up
:
Absorb spills with an inert material, clay granules or other inert absorbent material and put in
container for disposal. Use appropriate PPE.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling
:
Ensure good ventilation of the work station. Wear personal protective equipment.
Hygiene measures
:
Do not eat, drink or smoke when using this product. Always wash hands after handling the
product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions
:
Store in a well-ventilated place. Keep cool. Keep container closed when not in use. Keep only
in original container. Keep from freezing. Avoid excess heat.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Appropriate engineering controls
Appropriate engineering controls
:
Adequate ventilation systems as needed to control concentrations of airborne contaminants
below applicable threshold limit values.
Environmental exposure controls
:
Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Hand protection:
Protective gloves
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Safety Data Sheet
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Eye protection:
Not required for normal conditions of use
Skin and body protection:
It is recommended for handlers to wear appropriate clothing to prevent skin contact including long sleeves, long pants, socks and shoes.
Respiratory protection:
Not required for normal conditions of use
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
:
Liquid
Appearance
:
Milky white emulsion
Color
:
Milky white
Odor
:
Mild, Neutral
Odor threshold
:
No data available
pH
:
3.9 @ 25°C (77°F)
Melting point
:
No data available
Freezing point
:
Not applicable
Boiling point
:
No data available
Flash point
:
> 200 °C (> 392°F) PMCC
Relative evaporation rate (butyl acetate=1)
:
No data available
Flammability (solid, gas)
:
Non flammable.
Vapor pressure
:
No data available
Relative vapor density at 20 °C
:
No data available
Relative density
:
1.0072 @ 20°C (68°F)
Solubility
:
Dispersible
Log Pow
:
No data available
Auto-ignition temperature
:
Not applicable
Decomposition temperature
:
No data available
Viscosity, kinematic
:
Not applicable
Viscosity, dynamic
:
< 10 cP @ 20°C (68°F)
Explosion limits
:
Not applicable
Explosive properties
:
Not explosive
Oxidizing properties
:
Not applicable
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
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10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Adams Flea & Tick Home Spray
LD50 oral rat
> 5000 mg/kg
LD50 dermal rat
> 5000 mg/kg
pH
3.9 @ 25°C (77°F)
GHS-US Properties
Classification
Acute toxicity
Not classified
Skin corrosion/irritation
Not classified
Serious eye damage/irritation
Not classified
Respiratory or skin sensitization
Not classified
Germ cells mutagen
Not classified
Carcinogenicity
Not classified
Reproductive toxicity
Not classified
Specific target organ toxicant
(single exposure)
Not classified
Specific target organ toxicant
(repeated exposure)
Not classified
Aspiration hazard
Not classified
Potential health effects
Inhalation
Acute
:
Under normal conditions of use, no health effects are expected.
Skin
Acute
:
May cause mild skin irritation.
Chronic
:
Prolonged and repeated exposure to Etofenprox can cause skin irritation.
Eye
Acute
:
Under normal conditions of use, no health effects are expected.
Ingestion
Acute
:
Under normal conditions of use, no health effects are expected.
Mutagenicity
:
Etofenprox has been found negative for mutagenicity potential using the Ames test, chromosomal aberration and
micronucleus test methods, Piperonyl butoxide was not mutagenic in a battery of tests, (s)-Methoprene has been
tested and found negative for mutagenicity potential.
Carcinogenicity
:
Etofenprox is not classified as carcinogen by NTP, IARC and OSHA, Piperonyl butoxide is not classified as
carcinogen by NTP, IARC and OSHA, (s)-Methoprene is not classified as carcinogen by NTP, IARC and OSHA.
Reproductive Effects
:
Etofenprox did not produce teratogenic or reproductive effects in laboratory experiments, Piperonyl butoxide did not
produce any birth defects or adverse effects on reproductive parameters in tests with rats and rabbits, (s)-
Methoprene is not a reproductive toxin and does not cause birth defects.
SECTION 12: Ecological information
12.1. Toxicity
Etofenprox (80844-07-1)
LC50 Acute fish 1
0.0027 mg/l (Exposure time: 96h - Rainbow trout)
LC50 Acute fish 2
> 0.0165 (Exposure time: 96h - Sheepshead minnow)
LC50 Acute crustacea 1
0.0000188 mg/l (Exposure time: 96h - Mysid shrimp)
LC50 Acute crustacea 2
0.0008 mg/l (Exposure time: 48h - Daphnia magna)
NOEC Chronic crustacea 1
0.00017 mg/l (Daphnia magna)
Piperonyl butoxide (51-03-6)
LC50 Acute fish 1
1.9 mg/l (Exposure time: na - Rainbow trout)
LC50 Acute fish 2
3.94 mg/l (Exposure time: na - Sheepshead minnow)
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Piperonyl butoxide (51-03-6)
LC50 Acute crustacea 1
0.49 mg/l (Exposure time: na - Mysid shrimp)
LC50 Acute crustacea 2
0.51 mg/l (Exposure time: na - Gammarus fasciatus (amphipod))
NOEC Chronic fish 1
0.04 mg/l (Fathead minnow)
NOEC Chronic crustacea 1
0.03 mg/l (Daphnia magna)
(s)-Methoprene Technical (65733-16-6)
LC50 Acute fish 1
0.76 mg/l (Exposure time: 96h - Rainbow trout)
LC50 Acute fish 2
> 0.37 mg/l (Exposure time: 96h - Blue gill)
LC50 Acute crustacea 1
0.11 mg/l (Exposure time: 96h - Mysid shrimp)
LC50 Acute crustacea 2
0.36 mg/l (Exposure time: 48h - Daphnia magna)
NOEC Chronic fish 1
0.048 mg/l (Fathead minnow)
NOEC Chronic crustacea 1
0.014 mg/l (Mysid shrimp)
12.2. Persistence and degradability
Etofenprox (80844-07-1)
Persistence and degradability
Etofenprox is not readily biodegradable.
(s)-Methoprene Technical (65733-16-6)
Persistence and degradability
(s)-Methoprene degrades rapidly in sunlight, both in water and on inert surfaces. The pesticide
also is metabolized rapidly in soil and does not leach. Thus, it should not persist in soil or
contaminate ground water.
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
(s)-Methoprene Technical (65733-16-6)
Mobility in soil
Rapidly metabolized in soil under both aerobic and anaerobic conditions (half-life 10-14 days).
12.5. Other adverse effects
No additional information available
SECTION 13: Disposal considerations
13.1. Disposal methods
Product/Packaging disposal recommendations
:
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
SECTION 14: Transport information
UN number
Proper Shipping Name
Transport hazard
class(es)
Packing group
Environmental hazards
DOT
Not regulated
Not regulated
Not regulated
Not regulated
Not applicable
IMDG
UN3082
Packaging 5 L or greater:
Environmentally Hazardous substance,
Liquid, N.O.S. (Etofenprox)
9
III
Marine pollutant
IATA
UN3082
Packaging 5 L or greater:
Environmentally Hazardous substance,
Liquid, N.O.S. (Etofenprox)
9
III
Acute aquatic toxicity
SECTION 15: Regulatory information
15.1. US Federal regulations
Piperonyl butoxide (51-03-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
SARA Section 313 - Emission Reporting
1 %
FIFRA Labelling
Adams Flea & Tick Home Spray
Safety Data Sheet
05/18/2018
EN (English US)
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15.2. US State regulations
No additional information available
SECTION 16: Other information
Date of issue
:
03 November 2015
Revision date
:
18 May 2018
SDS US (GHS HazCom 2012) - CGP
The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient
verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS
MADE.
EPA Registration Number
2724-822-89459
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety
data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced
below. The pesticide label also includes other important information, including directions for use.
FIFRA Signal word
Caution
FIFRA Precautionary Statement
KEEP OUT OF REACH OF CHILDREN.
FIFRA Hazards to Humans and Domestic
Animals
Wear long-sleeved shirt and long pants, socks, shoes and gloves.