CHEMALERT REPORT
Full Report
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
Synonym(s) NSN: XXXX-66-150-9101
592939 TOUCH-N-PREP ALODINE 1132 • 6P 592939 - PRODUCT CODE • 6P 592939 TOUCH-N-PREP
ALODINE 1132 (FORMERLY) • 6P ALODINE 1132 TOUCH-N-PREP • 6P TOUCH-N-PREP ALODINE 1132
1.2 Uses and uses advised against
Use(s) AEROSPACE APPLICATIONS • TOUCH UP PAINT • TOUCH UP PEN
1.3 Details of the supplier of the safety data sheet
Supplier name AVIALL AUSTRALIA PTY LTD
Address 20-22 Lindaway Place, Tullamarine, VIC, Australia, 3043
Telephone (03) 9339 3030
Fax (03) 9338 9773
Email [email protected]
Website http://www.aviall.com
1.4 Emergency telephone number(s)
Emergency (03) 9339 3000
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
GHS Classification(s) Skin Corrosion/Irritation: Category 2
Serious Eye Damage / Eye Irritation: Category 2A
Carcinogenicity: Category 1B
2.2 Label elements
Signal word DANGER
Pictograms
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer.
Prevention statement(s)
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response statement(s)
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P321 Specific treatment is advised - see first aid instructions.
P332 + P337 + P313 If skin or eye irritation occurs: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before re-use.
Storage statement(s)
P405 Store locked up.
Page 1 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
Disposal statement(s)
P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other Hazards
No information provided.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
3.1 Substances / Mixtures
Ingredient CAS number EC number Content
CHROMIUM CHROMATE 24613-89-6 246-356-2 0.1-1%
CHROMIUM TRIOXIDE 1333-82-0 215-607-8 0.1-1%
WATER 7732-18-5 231-791-2 >60%
NON HAZARDOUS INGREDIENTS Not Available Not Available remainder
4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
First aid facilities Eye wash facilities and safety shower should be available.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment needed
No information provided.
Treat symptomatically.
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Use an extinguishing agent suitable for the surrounding fire.
5.2 Special hazards arising from the substance or mixture
Non flammable. May evolve toxic hexavalent chromium oxides when heated to decomposition.
5.3 Advice for firefighters
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those
downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use
waterfog to cool intact containers and nearby storage areas.
5.4 Hazchem code
●3Z
Alcohol resistant foam is the preferred firefighting medium
Z
3
Self Contained Breathing apparatus and protective gloves.
●
Foam
6. ACCIDENTAL RELEASE MEASURES
Page 2 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
6.1 Personal precautions, protective equipment and emergency procedures
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate area
where possible. Contact emergency services where appropriate.
6.2 Environmental precautions
Prevent product from entering drains and waterways.
6.3 Methods of cleaning up
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in
suitable containers for disposal.
6.4 Reference to other sections
See Sections 8 and 13 for exposure controls and disposal.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
7.2 Conditions for safe storage, including any incompatibilities
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Contamination with incompatibles may
cause fire or explosion. Ensure packages are adequately labelled, protected from physical damage and sealed when not in use.
7.3 Specific end use(s)
No information provided.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Substance Reference
TWA STEL
ppmppm mg/m³mg/m³
Chromium (VI) Compounds (as Cr), water
insoluble
SWA (AUS) -- 0.05 -- --
Chromium (VI) compounds SWA (AUS) -- 0.05 -- --
Biological limits
Ingredient Reference Determinant Sampling time BEI
CHROMIUM CHROMATE ACGIH BEI Total chromium in urine
End of shift at
end of
workweek
25 µg/L
ACGIH BEI Total chromium in urine
Increase during
shift
10 µg/L
CHROMIUM TRIOXIDE ACGIH BEI Total chromium in urine
End of shift at
end of
workweek
25 µg/L
ACGIH BEI Total chromium in urine
Increase during
shift
10 µg/L
8.2 Exposure controls
Engineering Controls
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction
ventilation is recommended. Maintain vapour levels below the recommended exposure standard.
PPE
Eye/Face Wear splash-proof goggles.
Hand Wear PVC or rubber gloves.
Body Wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type B (Inorganic gases and vapours) respirator.
Page 3 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance BROWN LIQUID
Odour MILD ODOUR
Odour Threshold NOT AVAILABLE
pH 2.2 to 2.5
Melting Point < 0°C
Boiling Point > 100°C
Flash Point NOT RELEVANT
Evaporation Rate AS FOR WATER
Flammability NON FLAMMABLE
Upper Explosion Limit NOT RELEVANT
Lower Explosion Limit NOT RELEVANT
Vapour Pressure 18 mm Hg @ 20°C
Vapour Density NOT AVAILABLE
Solubility (water) SOLUBLE
Partition Coefficient NOT AVAILABLE
Autoignition Temperature NOT AVAILABLE
Decomposition Temperature NOT AVAILABLE
Viscosity NOT AVAILABLE
Explosive Properties NOT AVAILABLE
Oxidising Properties NOT AVAILABLE
Specific Gravity 1.1 to 1.2
9.2 Other information
% Volatiles > 60 % (Water)
10. STABILITY AND REACTIVITY
10.1 Reactivity
Carefully review all information in sections 10.2 to 10.6.
10.2 Chemical stability
Stable under recommended conditions of storage.
10.3 Possibility of hazardous reactions
Polymerization is not expected to occur.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with combustible materials, reducing agents (e.g. sulphites), metals and some plastics and resins.
May evolve toxic hexavalent chromium oxides when heated to decomposition.
10.6 Hazardous decomposition products
Page 4 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Health hazard
summary
Harmful - irritant. This product has the potential to cause adverse health effects with over exposure. Use safe
work practices to avoid eye or skin contact and inhalation. May cause sensitisation by skin contact.
Hexavalent chromium compounds are classified as carcinogenic to humans (IARC Group 1).
Eye
Irritant. Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged
contact.
Inhalation
Irritant. Over exposure may result in irritation of the nose and throat, with coughing. Hexavalent chromium
compounds are classified as carcinogenic to humans (IARC Group 1).
Skin
Irritant. Contact may result in irritation, redness, rash and dermatitis. May be absorbed through skin with
harmful effects. May cause sensitisation by skin contact.
Ingestion
Harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea.
Ingestion of large quantities may result in dizziness, drowsiness and unconsciousness. Chronic exposure
may result in liver and kidney damage.
Toxicity data
CHROMIUM TRIOXIDE (1333-82-0)
LD50 (Ingestion): 80 mg/kg (rat)
LD50 (Intraperitoneal): 14 mg/kg (mouse)
LD50 (Intravenous): 9260 ug/kg (rat)
LDLo (Skin): 55 mg/kg (rat)
LDLo (Subcutaneous): 20 mg/kg (mouse)
TCLo (Inhalation): 110 ug/m³ (human)
TDLo (Intravenous): 5 mg/kg (hamster)
TDLo (Subcutaneous): 20 mg/kg (mouse)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradability
No information provided.
12.3 Bioaccumulative potential
No information provided.
12.4 Mobility in soil
No information provided.
12.5 Results of PBT and vPvB assessment
No information provided.
12.6 Other adverse effects
WATER: Chromium (VI) may be reduced to Chromium (III) by organic matter present in water, and may eventually deposit in
sediments. Toxic to microorganisms. May bioaccumulate. SOIL: Chromium in the soil may be transported from soil through runoff and
leaching of water. ATMOSPHERE: Chromium is primarily removed from the atmosphere by fallout and precipitation and may enter
surface water or soil.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Waste disposal
Add a solution of a mild reducing agent (thiosulphate, bisulphate or ferrous salt, but not carbon or sulphur) to
the product. A sulphite or ferrous salt will require addition of 3 M sulphuric acid to promote reduction.
Neutralise the solution with soda ash. Absorb with sand or similar and dispose of to an approved landfill site.
Contact the manufacturer/supplier for additional information (if required).
Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
Page 5 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
Land Transport Sea Transport Air Transport
(ADG) (IMDG/IMO) (IATA/ICAO)
14.1 UN number 3082 3082 3082
14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
14.3 Transport hazard classes
DG Class 9 99
Subsidiary risk(s) None Allocated --
14.4 Packing group III IIIIII
14.5 Environmental hazards None Allocated
14.6 Special precautions for user
Hazchem Code ●3Z
EMS F-A, S-F
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
Classified as a Schedule 6 Poison using the criteria in the Standard for the Uniform Scheduling of Medicines
and Poisons (SUSMP).
Carc. - Carcinogen
Xi - Irritant
Classifications
R36/38: Irritating to eyes and skin.
R49: May cause cancer by inhalation.
Risk phrases
S24/25: Avoid contact with skin and eyes.
S45:
In case of accident or if you feel unwell seek medical advice immediately (show the
label where possible).
S53: Avoid exposure - obtain special instructions before use.
S61: Avoid release to the environment. Refer to special instructions/safety data sheets.
Safety phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.
Inventory listing(s)
15.2 Chemical safety assessment
No information provided.
16. OTHER INFORMATION
Additional information
IARC GROUP 1 - CONFIRMED HUMAN CARCINOGEN. This product contains an ingredient for which there
is sufficient evidence to have been classified by the International Agency for Research into Cancer as a
human carcinogen. The use of products known to be human carcinogens should be strictly monitored and
controlled.
CHROMATES - CHROMIUM PRODUCTS: Asthma sufferers, respiratory impaired or previously sensitised
(respiratory or skin) individuals are advised to avoid all exposure to chromium or chromate based products.
CHROMIUM: The most common form of chromium found in nature and in biological materials is trivalent (III)
chromium which is poorly absorbed into the body. Chromium (VI) is readily absorbed where it is converted
intracellularly to the carcinogenic chromium (III) form. Chromium (VI) compounds are classified as
carcinogenic to humans (IARC Group 1). Chromium (III) is not classifiable as to its carcinogenicity in humans
(IARC Group 3).
Page 6 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
HEALTH EFFECTS FROM EXPOSURE:
It should be noted that the effects from exposure to this product will depend on several factors including:
frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used
and method of application. Given that it is impractical to prepare a ChemAlert report which would encompass
all possible scenarios, it is anticipated that users will assess the risks and apply control methods where
appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
The recommendation for protective equipment contained within this report is provided as a guide only.
Factors such as method of application, working environment, quantity used, product concentration and the
availability of engineering controls should be considered before final selection of personal protective
equipment is made.
COLOUR RATING SYSTEM: RMT has assigned all ChemAlert reports a colour rating of Green, Amber or
Red for the sole purpose of providing users with a quick and easy means of determining the hazardous
nature of a product. Safe handling recommendations are provided in all ChemAlert reports so as to clearly
identify how users can control the hazards and thereby reduce the risk (or likelihood) of adverse effects. As
a general guideline, a Green colour rating indicates a low hazard, an Amber colour rating indicates a
moderate hazard and a Red colour rating indicates a high hazard.
While all due care has been taken by RMT in the preparation of the Colour Rating System, it is intended as a
guide only and RMT does not provide any warranty in relation to the accuracy of the Colour Rating System.
As far as is lawfully possible, RMT accepts no liability or responsibility whatsoever for the actions or
omissions of any person in reliance on the Colour Rating System.
Abbreviations
ACGIH American Conference of Governmental Industrial Hygienists
CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
CNS Central Nervous System
EC No. EC No - European Community Number
EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
GHS Globally Harmonized System
GTEPG Group Text Emergency Procedure Guide
IARC International Agency for Research on Cancer
LC50 Lethal Concentration, 50% / Median Lethal Concentration
LD50 Lethal Dose, 50% / Median Lethal Dose
mg/m³ Milligrams per Cubic Metre
OEL Occupational Exposure Limit
PEL Permissible Exposure Limit
pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
ppm Parts Per Million
REACH Regulation on Registration, Evaluation, Authorisation and Restriction of Chemicals
STEL Short-Term Exposure Limit
STOT-RE Specific target organ toxicity (repeated exposure)
STOT-SE Specific target organ toxicity (single exposure)
SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
SWA Safe Work Australia
TLV Threshold Limit Value
TWA Time Weighted Average
Report Status
This ChemAlert report has been independently compiled by RMT's scientific department utilising the original
Safety Data Sheet ('SDS') for the product provided to RMT by the manufacturer. The information is based on
the latest chemical and toxicological research and is believed to represent the current state of knowledge as
to the appropriate safety and handling precautions for the product at the time of issue. It is an independent
collation by RMT of information obtained from the original SDS for this product. Its content has not been
authorised or verified by the manufacturer / distributor of the chemical to which it relates.
This ChemAlert report does not constitute the manufacturer's original SDS and is not intended to be a
replacement for same. It is provided to subscribers of ChemAlert as a reference tool only, is not all-inclusive
and does not represent any guarantee as to the properties of the product. Further clarification regarding any
aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this ChemAlert report, it
does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no
Page 7 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
CHEMALERT REPORT
Full Report
Product name 6P 592939 ALODINE 1132 TOUCH-N-PREP COATING
liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by
any person as a consequence of their reliance on the information contained in this ChemAlert report.
Prepared By
Risk Management Technologies
5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: [email protected]
Web: www.rmt.com.au
Last Reviewed:12 Sep 2013
Date Printed:06 Mar 2015
11 Aug 2011
End of Report
Based on SDS dated:
Page 8 of 8
Reviewed: 12 Sep 2013
Printed: 06 Mar 2015
This report was compiled based on the SDS dated 11 Aug 2011
